Synthesis and characterization of novel Cu (II) and Zn (II) complexes of 5-{[(2-Hydroxyethyl) sulfanyl] methyl}-8-hydroxyquinoline as effective acid corrosion inhibitor by experimental and computational testings

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題名:	Synthesis and characterization of novel Cu (II) and Zn (II) complexes of 5-{[(2-Hydroxyethyl) sulfanyl] methyl}-8-hydroxyquinoline as effective acid corrosion inhibitor by experimental and computational testings
作者:	Rbaa, M;Benhiba, F;Galai, M;Abousalem, AS;Ouakki, M;Lai, CH;Lakhrissi, B;Jama, C;Warad, I;Touhami, ME;Zarrouk, A
關鍵詞:	Synthesis;Complexes;Electrochemical techniques;ICP-OES/SEM;DFT/MD simulations
日期:	2020
上傳時間:	2022-08-09T08:09:38Z (UTC)
出版者:	ELSEVIER
ISSN:	0009-2614
摘要:	Two new complexes were synthesized, characterized and tested as inhibitors for mild steel corrosion in 1.0 M HCl. The anticorrosive effect has been studied using the potentiodynamic polarization (PDP) and impedance spectroscopy (EIS). The inhibitory efficiency increases with increasing concentration to reach 96.0% for Q-Cu and 94.6% for Q-Zn at 10(-3) M. The two inhibitors are mixed type and follows the Langmuir isotherm adsorption. The surface of the mild steel has been examined by SEM/EDS and the corrosive solution by ICP-OES. DFT calculations and molecular dynamic simulation (MD) show a good correlation with the experimental results for both complexes.
URI:	http://dx.doi.org/10.1016/j.cplett.2020.137771 https://www.webofscience.com/wos/woscc/full-record/WOS:000560720900014 https://ir.csmu.edu.tw:8080/handle/310902500/24888
關聯:	CHEMICAL PHYSICS LETTERS ,2020 ,v754
顯示於類別:	[中山醫學大學研究成果] 期刊論文

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